故事發生在上世紀三十年代的南京，于水村（佟大為 飾）是一位年輕有為的畫家，一場意外中，他邂逅了名為桃枝（孫儷 飾）的歌女。隨著時間的推移，桃枝的美麗和正直吸引了于水村的注意，兩人漸漸走到了一起。 然而，性格和身份的巨大差異讓于水村和桃枝之間矛盾重重，最終，一對有情人分道揚鑣。之后，桃枝成為了銀行大亨的妻子，而目睹這一切的于水村只得利用酒精來平息心中的痛苦。可是，于水村并不知道的是，桃枝在內心里依然深愛著他，為了保全他，她甚至愿意犧牲自己的性命。桃枝的妹妹李小桃（楊冪 飾）是一名歌女，不滿自己身份的她一心想要進駐上流社會，卻為此付出了慘痛的代價。
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